JPyro – Issue 27, Winter 2008 – Contents

Full Papers: Copper in Pyrotechnics The Debris Hazard from Fireworks Held in Steel ISO Containers Movement Dynamics Of Firework Shells Fired From Mortars Comparison of 6-DOF Trajectory Model with Modified Linear Theory for Bullets Metal–Fluorocarbon Pyrolants: VIII.1‡ Behavior of Burn Rate and Radiometric Performance of two Magnesium/Teflon/Viton (MTV) Formulations upon Addition of Graphite A Thermokinetic …
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Metal–Fluorocarbon Pyrolants: VIII.1‡ Behavior of Burn Rate and Radiometric Performance of two Magnesium/Teflon/Viton (MTV) Formulations upon Addition of Graphite§

Ernst-Christian Koch Abstract: The burn rate, u (mm s−1) of fuel rich magnesium/Teflon/Viton (MTV) is increased by 23-36 % upon addition of 5 wt% graphite whereas the spectral efficiency Eβ (J g−1 sr−1) remains largely unaffected. Keywords: Burn rate, graphite, magnesium, MTV, polytetrafluoroethylene, radiometry, TeflonTM, VitonTM Ref: JPyro, Issue 27, 2008, pp38-41 (J27_38)

Movement Dynamics Of Firework Shells Fired From Mortars

V. Ya. Yakovlev and S. K. Chankaev Abstract: Experimental investigations were carried out using 125 and 310 mm firework shells. The pressures in a mortar during firing were measured. A mathematical model of the firing action concerning low pressure in the space behind the shell was developed. Here it is supposed that non-simultaneous processes of ignition …
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Comparison of 6-DOF Trajectory Model with Modified Linear Theory for Bullets

Dimitrios N. Gkritzapis, Elias E. Panagiotopoulos, Dionissios P. Margaris and Dimitrios Papanikas Abstract: A modified linear model is proposed for fast and accurate prediction of short and long-range trajectories of spin-stabilized bullets via atmospheric flight to a final impact point. This model is compared with a full 6-DOF trajectory model. The computational flight analysis takes …
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The Debris Hazard from Fireworks Held in Steel ISO Containers

Roy Merrifield and Peter Allan Moreton Abstract: A number of serious accidents in European Union countries involving explosions of fireworks stored in steel ISO freight containers has shown that the hazards associated with bulk-stored fireworks might be greater than previously thought. To address this problem an EU research programme was initiated, part of which involved …
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Copper in Pyrotechnics

Georg Steinhauser, Karina Tarantik and Thomas M. Klapötke Abstract: Copper compounds play a key role in the development of “greener” pyrotechnics by substitution of noxious barium compounds from green colored effects. The application of many copper(ii) compounds in pyrotechnics is limited because of their noble and often hygroscopic character. We have investigated nitratocuprates(ii) as well …
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JPyro – Issue 26, Winter 2006 – Contents

Full Papers: Atmospheric Flight Dynamic Simulation Modeling of Spin-Stabilized Projectiles Atmospheric Flight Dynamic Simulation Modeling of Spin-Stabilized Projectiles and Small Bullets with Constant Aerodynamic Coefficients Selected Proccedings of the 5th Workshop on Pyrotechnic Combustion Mechanisms: Introduction Ignition and Combustion of Aluminum in High Explosives Ignition And Burning Rate Characteristics Of Pyrolant Black Powder Laser diode …
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Thermal Stability of Hydrazinium Nitroformate (HNF) Assessed by Heat Generation Rate and Heat Generation and Mass Loss

Manfred A. Bohn Abstract: HNF, hydrazinium nitroformate, H3NNH2 +·C(NO2)3−, is a water soluble salt. It has a positive oxygen balance of 13%, a much more positive enthalpy of formation than ammonium perchlorate (AP) and amuch higher heat of explosion than AP, 5579 J g−1 against 1972 J g−1. Additionally it has no chlorine and all …
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Synthesis, Structural and Reactive Characterization of Miscellaneous Nanothermites

Denis Spitzer and Marc Comet Abstract: In this paper, we report the elaboration and the characterization of several kinds of nanothermites made at the French German Research Institute of Saint‑Louis (ISL). Three types of materials are presented herein: tungsten trioxide based nanothermites obtained by physical mixing of this metallic oxide withaluminum nanoparticles; tungsten trioxide based …
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Laser Diode Ignition of Pyrotechnic Mixtures: Experimental and Numerical Studies

Pr Philippe Gillard Abstract: An experimental study of laser ignition of Zr/KClO4, Zr/PbCrO4, Fe/KClO4, Fe/KNO3, B/KClO4 and B/KNO3 mixtures is presented in this paper. The ignition system is composed of two lenses which focus the laser beam on the tablet. A sapphire porthole, juxtaposed with the pyrotechnic composition, protects the optical unit but causes losses …
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